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August 22, 2025Advanced Synthesis & CatalysisOpen Access

CO2‐to‐Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst

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Authors

EÁElena Álvarez‐RuizMNMarta NavarroISIgnacio Sancho

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Overview

Mechanochemical synthesis of Ti(III) catalyst shows superior efficiency in producing cyclic carbonates from CO2 and epoxides, indicating a new approach to CO2 valorization.

Key Points

  • The study demonstrates the efficient conversion of CO2 to cyclic carbonates using a Ti(III) catalyst under atmospheric pressure, enhancing sustainable chemistry.
  • Catalysis exhibited by the Ti(III) complex allows for the formation of cyclic carbonates from various epoxides, significantly advancing CO2 utilization techniques.
  • Assessment using density functional theory reveals critical steps in the catalytic mechanism, including epoxide coordination and CO2 insertion.
  • The findings suggest that Ti(III) oxidation state plays a vital role in improving catalytic performance, with further implications for industrial applications.

Cite This Study

Álvarez‐Ruiz et al. (2025) studied this question.

synapsesocial.com/papers/68af570dad7bf08b1eaddfb4https://doi.org/10.1002/adsc.70057
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