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December 6, 2025ACS Applied Materials & Interfaces

Harnessing the Synergistic Effect of Acidic and Basic Sites in Nitrogen-Enriched α-TiP for Co-Catalyst-Free Selective CO 2 Cycloaddition

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Authors

LSLovjeet SinghPRPawan Rekha

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Overview

Nitrogen-enriched bifunctional titanium phosphate catalyst shows >99% conversion in CO2 cycloaddition, indicating high stability and catalytic performance without cocatalysts.

Key Points

  • Catalytic performance achieved over 99% conversion and selectivity toward cyclic carbonates.
  • Activation energy measured at 9.06 kcal mol-1 supports the efficient mechanism proposed.
  • The catalyst demonstrated stability over five cycles, retaining high yield throughout.
  • This cocatalyst-free approach highlights the potential for sustainable CO2 conversion applications.

Cite This Study

Singh et al. (2025) studied this question.

synapsesocial.com/papers/69337cfbb3f947a0a125a760https://doi.org/10.1021/acsami.5c14890
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