Synthesis of N-Alkylated Amines via Alcohol Dehydrogenation Catalyzed by a Bis-Azo-Diamido Coordinated Ruthenium(III) Complex

Supriyo Halder; Srijita Naskar; Shahnaz S. Malik; Dipika Roy; Kausikisankar Pramanik

doi:10.1039/d5dt01716e

January 1, 2025Dalton Transactions

Synthesis of N-Alkylated Amines via Alcohol Dehydrogenation Catalyzed by a Bis-Azo-Diamido Coordinated Ruthenium(III) Complex

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Key Points

N-alkylated amines were synthesized effectively, demonstrating the utility of the ruthenium catalyst in organic reactions.
The catalyst trans-[Ru(H2L)Cl(PPh3)] operates under stable conditions, enhancing synthesis efficiency with high robustness.
Synthesis employed a redox-active tetradentate bipyridine ligand, providing structural integrity crucial for the reaction process.
This study highlights the significance of ruthenium coordination complexes in developing efficient synthetic methodologies.

Implication

Catalyst trans-[Ru(H2L)Cl(PPh3)] improves amine synthesis from alcohol, indicating potential in organic reactions.

Abstract

An interesting ruthenium(III) complex, trans-[Ru(H2L)Cl(PPh3)], has been synthesized using a redox-active tetradentate bis-azo diamine ligand (H4L). This complex represents the first example of a structurally robust, air- and moisture-stable coordination...

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Cite This Study

Halder et al. (2025) studied this question.

synapsesocial.com/papers/68af63d7ad7bf08b1eae3d73 https://doi.org/10.1039/d5dt01716e

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Synthesis of N-Alkylated Amines via Alcohol Dehydrogenation Catalyzed by a Bis-Azo-Diamido Coordinated Ruthenium(III) Complex

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis of N-Alkylated Amines via Alcohol Dehydrogenation Catalyzed by a Bis-Azo-Diamido Coordinated Ruthenium(III) Complex

Key Points

Implication

Abstract

Discussion

Cite This Study

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