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September 5, 2025physica status solidi (a)

Comparative Investigation of the Critical Role of Mn, Zn, and Mn/Zn Co‐Doping in Modulating Local Coordination Environment, Magnetic Behavior, and Supercapacitor Performance of α‐Cu2V2O7

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Authors

ADAshok Kumar DasRLRashbihari LayekSMS. Mukherjee

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Overview

This analysis demonstrates how Mn and Zn co-doping modulates local coordination and enhances supercapacitor performance.

Key Points

  • Mn/Zn co-doping enhances the electrochemical performance of α-Cu2V2O7, leading to superior specific capacitance.
  • Structural analysis confirms the integration of Mn and Zn at Cu sites, disrupting super-exchange pathways.
  • Temperature-dependent studies show a slight decrease in Néel temperature with co-doping, implying altered magnetic properties.
  • Vibrational studies indicate significant variations in CuO bond lengths, contributing to improved charge storage capabilities.

Cite This Study

Das et al. (2025) studied this question.

synapsesocial.com/papers/68bb49cc6d6d5674bccffac0https://doi.org/10.1002/pssa.202500491
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