Photocatalytic 1,2-Aminoformylation of Olefins with Bifunctional Oxime Esters

Fang Zheng; Zhidong Wan; Xu‐Jia Wang; Yihan Zhang; Feng Chen; Hong Qin; Yang Zhao

doi:10.1039/d5ob01147g

January 1, 2025Organic & Biomolecular Chemistry

Photocatalytic 1,2-Aminoformylation of Olefins with Bifunctional Oxime Esters

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Key Points

The method enables single-step synthesis of β-amido acetals from alkenes under mild conditions.
It utilizes bifunctional oxime esters, enhancing regioselectivity in the transformation.
The strategy is metal-free, promoting environmentally friendly synthetic practices.
The approach highlights advancements in photochemical methodologies for complex organic synthesis.

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Implication

This method demonstrates the regioselective difunctionalization of alkenes, implying a novel approach using bifunctional oxime esters.

Abstract

Here, we disclose a metal-free photochemical strategy for the single-step synthesis of β-amido acetals through the regioselective difunctionalization of alkenes using bifunctional oxime esters. This method operates under mild conditions...

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Zheng et al. (2025) studied this question.

synapsesocial.com/papers/68bb5f076d6d5674bcd02d5e https://doi.org/10.1039/d5ob01147g

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Photocatalytic 1,2-Aminoformylation of Olefins with Bifunctional Oxime Esters

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Photocatalytic 1,2-Aminoformylation of Olefins with Bifunctional Oxime Esters

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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