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Bond Dissociation Energies of RuC, RhC, OsC, IrC, and PtC Measured by Resonant Three-Photon Ionization Spectroscopy

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Bond dissociation energies of RuC, RhC, OsC, IrC, and PtC were measured using resonant three-photon ionization spectroscopy.
D0 values for these carbides were found to range from 6.007 to 6.427 eV, with precise error estimates.
Analysis involved the use of two tunable lasers to measure high bond dissociation energies in the transition metal carbides.
A new electronic state of PtC was tentatively assigned, potentially offering insight into the chemical bonding of these compounds.

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Resonant three-photon ionization spectroscopy measures bond dissociation energies in transition metal carbides, revealing new electronic states.

Tomchak et al. (2025) studied this question.

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Resonant three-photon ionization spectroscopy measures bond dissociation energies in transition metal carbides, revealing new electronic states.