Thermochemical properties of small rhenium molecules: ReC, ReN, ReO, ReS, and ReC2

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Resonant two-photon ionization reveals bond dissociation energies in rhenium compounds, suggesting unique thermochemical characteristics.

Bond dissociation energies measured as D0(ReC) = 5.731 eV and others in rhenium compounds.
First measurements of thermochemical properties including bond dissociation and ionization energies reported.
Analysis using density functional theory and high-level composite methods determined electronic structure characteristics.
Research highlights unique thermochemical behaviors and trends across different rhenium-containing molecules.

Tomchak et al. (2025) studied this question.

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