Synthesis of N-PAHs revealed linear correlations in Zn 2+ binding and Hammett constants, suggesting implications for complexation.
N -PAHs 1a–f with varied substituents were synthesized. Substituent effects showed linear correlations among Hammett constants ( σ ), HOMO/LUMO levels, and log K a for Zn 2+ binding, while optical properties followed an inverted V -trend.
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Bai et al. (2025) studied this question.
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