Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

Renhua Su; Jiantao Zhang; Jiang Yan-fu; Xian Jiang; Peng Zhou; Jingxing Jiang; Weibing Liu

doi:10.1039/d5gc02911b

January 1, 2025Green Chemistry

Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

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Key Points

This method achieves regioselective synthesis of α,β-bisperoxides through a visible-light-driven reaction.
Using TBHP as a source of tert-butylperoxy and hydroperoxy groups proves novel in radical chemistry.
The study uncovers a new application for TBHP in facilitating peroxidation reactions without traditional methods.
Visible light plays a crucial role in driving the bisperoxidation of aryl alkenes, opening new synthesis pathways.

Implication

Visible-light-driven bisperoxidation enables regioselective synthesis of α,β-bisperoxides from alkenes, indicating a novel use of TBHP.

Abstract

We report a visible-light-driven bisperoxidation of aryl alkenes using TBHP, enabling the regioselective synthesis of α,β-bisperoxides. This represents the first radical reaction using TBHP as source of tert -butylperoxy and hydroperoxy groups.

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Cite This Study

Su et al. (2025) studied this question.

synapsesocial.com/papers/68c1ae7054b1d3bfb60e6332 https://doi.org/10.1039/d5gc02911b

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Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

Key Points

Implication

Abstract

Discussion

Cite This Study

Visible light-driven regioselective tert-butyl peroxidation and hydroperoxidation of alkenes using TBHP

Key Points

Implication

Abstract

Discussion

Cite This Study

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