Observation of Double-Ring Tubular B20(CO)n+ (n = 1–8)：Emergence of 2D-to-3D Transition in Boron Carbonyl Complexes

Hong Niu; Qiang Chen; Rui‐Nan Yuan; Qin-Wei Zhang; Si‐Dian Li

doi:10.1039/d5cp01827g

January 1, 2025Physical Chemistry Chemical Physics

Observation of Double-Ring Tubular B20(CO)n+ (n = 1–8)：Emergence of 2D-to-3D Transition in Boron Carbonyl Complexes

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Key Points

The emergence of 2D-to-3D transition in boron carbonyl complexes highlights a significant structural change.
Double-ring tubular structures B20(CO)n+ were observed, indicating their unique geometric properties.
This research utilizes joint chemisorption experiments to probe the interactions within boron-carbonyl frameworks.
Understanding these structures may pave the way for advancements in nanotechnology and material science.

Implication

Experimental observation of double-ring tubular carbonyl complexes shows a 2D-to-3D transition, suggesting new insights into boron structures.

Abstract

The consecutive discoveries of double-ring (DR) tubular D10d B20 and D2d B20+ as embryos of single-walled boron nanotubes have attracted considerable attention in the past two decades. Joint chemisorption experiment...

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Niu et al. (2025) studied this question.

synapsesocial.com/papers/68c1afb954b1d3bfb60e714b https://doi.org/10.1039/d5cp01827g

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Observation of Double-Ring Tubular B20(CO)n+ (n = 1–8)：Emergence of 2D-to-3D Transition in Boron Carbonyl Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

Observation of Double-Ring Tubular B20(CO)n+ (n = 1–8)：Emergence of 2D-to-3D Transition in Boron Carbonyl Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

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