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This is a Experimental Study study.

Visible-Light-Mediated Divergent Difunctionalization of gem-Difluoroalkenes Using Aryldiazonium Tetrafluoroborates

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Study shows efficient difunctionalization of gem-difluoroalkenes using sodium metabisulfite, suggesting new routes for organofluorine synthesis.

The strategy achieved moderate to excellent yields for several sulfone derivatives, enhancing organofluorine chemistry.
Results indicate the successful synthesis of β-hydroxy, β-alkoxy, and β-formyloxy sulfones from gem-difluoroalkenes.
Utilization of photocatalytic methods effectively diversifies functionalization routes for complex organic synthesis.
Chloroform allows for the production of β-hydroxy and β-alkoxy trichloromethyl compounds, broadening the methodology.

Zheng et al. (2025) studied this question.

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View Full Paper

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Authors

Study shows efficient difunctionalization of gem-difluoroalkenes using sodium metabisulfite, suggesting new routes for organofluorine synthesis.

The strategy achieved moderate to excellent yields for several sulfone derivatives, enhancing organofluorine chemistry.
Results indicate the successful synthesis of β-hydroxy, β-alkoxy, and β-formyloxy sulfones from gem-difluoroalkenes.
Utilization of photocatalytic methods effectively diversifies functionalization routes for complex organic synthesis.
Chloroform allows for the production of β-hydroxy and β-alkoxy trichloromethyl compounds, broadening the methodology.

Zheng et al. (2025) studied this question.

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