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September 21, 2025ACS OmegaOpen Access

Highly Selective Synthesis of ctt-1,5,9-Cyclododecatriene from 1,3-Butadiene via Nitrogen-Ligand-Supported Titanium Catalysts: Experimental Optimization and Mechanistic Insights

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Authors

HJH. Y. JiaSHS. HUANGWGWensi Guo

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Overview

Experimental optimization achieves 93% yield of 1,5,9-cyclododecatriene in 1,3-butadiene oligomerization, indicating effective catalytic activity and mechanistic insights.

Key Points

  • Achieving 93% yield of 1,5,9-cyclododecatriene demonstrates effective catalytic activity under optimized conditions.
  • The nitrogen-ligand-supported titanium catalysts enhance oligomerization of 1,3-butadiene, improving conversion rates significantly.
  • Density functional theory calculations elucidate the mechanism and confirm the high selectivity of the synthesized product.
  • This catalytic system offers a green approach for synthesizing 1,5,9-cyclododecatriene, contributing to lightweighting applications in industry.

Cite This Study

Jia et al. (2025) studied this question.

synapsesocial.com/papers/68d46cbf31b076d99fa6889chttps://doi.org/10.1021/acsomega.5c06983
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