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This is a Experimental Study study.

Rh(III)-catalyzed Oxidative C-H Cross-Coupling between Indoles and Thiophenes/Furanes

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This research demonstrates Rh(III)-catalyzed cross-dehydrogenative coupling of indoles with thiophenes, implying efficient biheteroarene synthesis.

The reaction showcases a novel method for synthesizing biheteroarenes through Rh(III)-catalyzed coupling.
A quinoline auxiliary is utilized, resulting in a mild reaction environment that prevents side reactions.
The approach leverages oxidative C-H cross-coupling to achieve functionalization of indoles with thiophenes and furanes.
This innovative synthesis method opens new pathways for developing complex molecular architectures in organic chemistry.

Wang et al. (2025) studied this question.

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This research demonstrates Rh(III)-catalyzed cross-dehydrogenative coupling of indoles with thiophenes, implying efficient biheteroarene synthesis.