Stabilization of Double Sandwich Structure of Mercury(II) Porphyrins: Hg•••Hg•••Hg Interactions and Structure-Function Correlation

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This is a Experimental Study study.

Anindya Sarkar; Dolly Chandel; Mirza Nasib Begg; Anjani K. Pandey; Nityananda Dutta; Chandrani Pal; Mohammad Usman; Anindya Datta; Sankar Prasad Rath

doi:10.1039/d5qi01593f

January 1, 2025Inorganic Chemistry Frontiers

Stabilization of Double Sandwich Structure of Mercury(II) Porphyrins: Hg•••Hg•••Hg Interactions and Structure-Function Correlation

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Key Points

Stable trinuclear complexes were successfully formed using different porphyrin frameworks, enhancing understanding of structure-function relationships.
Hg•••Hg•••Hg interactions play a vital role in stabilizing the double sandwich structure, providing insights into multi-metal coordination.
This research identified how the flexibility of the porphyrin frameworks impacts the stability and function of the complexes.
The findings can lead to advancements in the design of metal-based therapeutics by understanding coordination chemistry better.

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Implication

Research demonstrates stable trinuclear complexes of mercury porphyrins, indicating crucial structure-function correlations.

Abstract

A series of stable trinuclear "double sandwich" complexes of mercury(II) porphyrins having linear Hg3 core have been stabilized successfully utilizing both flexible and rigid porphyrin dimer frameworks. The gross structural...

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Sarkar et al. (2025) studied this question.

synapsesocial.com/papers/68d9052541e1c178a14f541a https://doi.org/10.1039/d5qi01593f

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Stabilization of Double Sandwich Structure of Mercury(II) Porphyrins: Hg•••Hg•••Hg Interactions and Structure-Function Correlation

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Abstract

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Cite This Study

Stabilization of Double Sandwich Structure of Mercury(II) Porphyrins: Hg•••Hg•••Hg Interactions and Structure-Function Correlation

Key Points

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Implication

Abstract

Discussion

Cite This Study

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