The spectral analysis program FEFF has been used to address a series of x-ray spectroscopic results from cerium based materials. Specifically, the experimental results of the M4,5 x-ray emission spectroscopy (XES) of γ-Ce, the M4,5 x-ray absorption spectroscopy of γ-Ce, and the L3 XAS of CeO2 are simulated with FEFF, with varying degrees of success. Cerium’s role as a surrogate for Pu is introduced and the strengths and shortcomings of the FEFF computational results will be noted.
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James Tobin (2024) studied this question.
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