The Alkynyl π Bond of sp-C Enhanced Rapid, Reversible Li–C Coupling to Accelerate Reaction Kinetics of Lithium Ions

Graphdiyne (GDY) is a promising anode for rechargeable batteries with high capacity, outstanding cyclic stability, and low diffusion energy. The unique structure of GDY endows distinctive mechanisms for metal-ion storage, and it is of great significance to further visualize the complex reaction kinetics of the redox process. Here, we systematically tracked the reaction kinetics and provided mechanistic insights into the lithium ions in the GDY to reveal the feature of the cation-π effect. It has been demonstrated that, unlike only one π bond in sp