The synthesis of porous organic polymers (POPs) based on a polymer of intrinsic microporosity (PIM), which represent a new class of promising materials, has been studied in detail. These porous systems are formed by precise joining of organic building blocks through covalent bonds in order to create predefined assemblies and can possess a three-dimensional (3D) or 2D-layered structure. The model reactions are considered and porosimetry studies are performed for the resulting POPs.
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Ponomarev et al. (2024) studied this question.
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