Fate and transport of chlorine dioxide: Modeling chlorine dioxide in water distribution systems

This study aims to conduct a comprehensive analysis of switching disinfectants from sodium hypochlorite bleach to chlorine dioxide (ClO 2 ) in the water distribution system of Geyikbayiri, Antalya. For this purpose, bulk decay rates of ClO 2 at various water temperatures were determined in laboratory studies. The study revealed ClO 2 bulk decay rates of 0.12639 day −1 , 0.17848 day −1 , and 0.19621 day −1 at temperatures 15°C, 20°C, and 30°C, respectively. The EPANET, a widely employed computer program for simulating the extended‐period behavior of hydraulic and water quality in pressurized pipes, was utilized for the analysis of the fate and transport of ClO 2 . A hydraulic model was first developed, calibrated, and verified using distinct data sets. The Hazen‐Williams friction coefficient of the PSA was determined to be 120 by the trial‐and‐error method with a mean absolute error (MAE) of 0.408 m. A ClO 2 model was then integrated with the calibrated and verified hydraulic model, revealing a wall decay rate of 0.01 m/day and an average MAE of 0.034 mg/l. After calibration and verification of the ClO 2 model, several management scenarios were developed, and ClO 2 dosing rates were determined. The study showed that ClO 2 dosing rates of 0.40 mg/l and 0.45 mg/l should be applied to keep ClO 2 concentrations within certain limits. Practitioner Points Disinfectants must maintain a sufficient residual in water distribution systems. Chlorine dioxide requires less contact time and is not affected by pH fluctuations. Modeling serves as a decision‐making tool for the management of disinfectants. Bulk and wall decay rates of chlorine dioxide are crucial for management strategies. Chlorine dioxide is a good alternative as a disinfectant in such systems.