Key points are not available for this paper at this time.
A chiral Brønsted acid/Pd that cooperatively catalyzed the asymmetric cascade aza-Piancatelli rearrangement/hydroamination of readily accessible alkynyl-functionalized tertiary furylcarbinols with anilines has been developed. This protocol provides expedient access to a variety of densely functionalized cyclopentabpyrroline derivatives in high yields with excellent enantioselectivities.
Nie et al. (Wed,) studied this question.