Analysis of particles containing alpha emitters in stagnant water in Fukushima Daiichi Nuclear Power Station’s Unit 3 reactor building

Particles containing alpha (α) nuclides were identified from sediment in stagnant water in the Unit 3 reactor building of the Fukushima Daiichi Nuclear Power Station (FDiNPS). We analyzed different concentrations of α-nuclide samples collected at two sampling sites, the torus room and the main steam isolation valve (MSIV) room. The solids in the stagnant water samples were classified, and the uranium (U) and total alpha concentrations of each fraction were measured by dissolution followed by inductively coupled plasma mass spectrometry and α-spectrometry. Most of the α-nuclides in the stagnant water samples from the torus and MSIV rooms were in particle fractions larger than 10 μm. We detected uranium-bearing particles ranging from sub-µm to 10 µm in size by scanning electron microscopy-energy-dispersive X-ray (SEM-EDX) observations. The chemical forms of U particles were determined in U-Zr oxides, oxidized UO