Quantification of regulated metals in recycled post-consumer polypropylene through comparative ICP-MS, AAS and LIBS analyses

Knowing the exact heavy metal load of recycled plastics is important for their risk assessment. We therefore established a novel strategic hierarchy for testing the heavy metal load of recycled plastics. For preliminary screening for unusually high elemental loads, laser-induced breakdown spectroscopy (LIBS) is suggested, while inductively coupled plasma-mass spectrometry (ICP-MS) or electrothermal atomic absorption spectroscopy (ETAAS) are used for exact quantification. The contents of ten regulated elements (Hg, As, Cd, Cr, Co, Cu, Se, Pb, Sn and Ni) in post-consumer (PCR), post-industrial (PIR), and virgin polypropylene (PP) were thus determined. Concentrations in the PCR were mostly found to be two orders of magnitude smaller than their threshold in non-food applications. Cu was most abundant in PCR with 18.7±6.1 mg/kg. Concentration variations of approx. 30 %. were found within a PCR batch, while between batches, slightly higher variations of 30 to 40 % were observed. Moreover, the heavy metal concentration patterns of PCR and PIR differ significantly. This strategy may enhance the applicational possibilities for PCR.