A synthetic method for the enantioselective and regiodivergent synthesis of hexahydro-2H-2,4a-methanonaphthalen-4-yl and octahydro-2,4-methanoazulen-1-yl esters that relies on the gold(I)- and chiral Brønsted acid-catalyzed cycloisomerization/Diels–Alder (CDA) reaction of (E)-1,10-dien-4-yn-3-yl acetates is described.
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Rojas et al. (2024) studied this question.
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