A Flow Injection Amperometric Sensor for Nitrate Detection Based on Cu Foam/Ordered Mesoporous Carbon Modified Glassy Carbon Electrode

Nitrate (NO 3 − ) contamination from agricultural and industrial waste affects environmental water quality and can cause severe diseases if consumed in drinking water. Therefore, the detection of NO 3 − is a necessary precaution. This work describes the development of an electrochemical sensor for NO 3 − detection that combines the advantages of ordered mesoporous carbon (OMC) and copper foam (Cu foam) on a glassy carbon electrode (Cu foam/OMC/GCE). The large surface area, uniform pore structure, and large pore volume of OMC supported the electrodeposition of Cu foam to create a highly porous electrocatalytic structure for NO 3 − reduction. Under optimal conditions, the developed electrochemical sensor exhibited linearity from 1.0 μM to 5.0 mM and a detection limit of 1.0 μM (S/N=3). Moreover, the proposed electrochemical sensor exhibited acceptable selectivity, and good stability and reproducibility. The developed sensor detected NO 3 − in drinking water samples with recoveries of 88.2±0.9 to 112.5±6.3 %.