Daphnezomines A, B, and dapholdhamine B, belongs to Daphniphyllum alkaloids, structurally features a unique azaadamantane core skeletons and eight contiguous stereocenters, including two quaternary carbon centers. In this review, total syntheses of those natural products by three groups.
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Nariyoshi Umekubo (2024) studied this question.
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