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October 11, 2025Green Chemistry

Photoinduced copper-catalyzed cross coupling of epoxides and alkynes via radical anions

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This method improves the efficiency of cross coupling reactions, enhancing synthetic pathways.
The study shows that epoxides can be effectively transformed into higher-value compounds using copper catalysis.
Radical anion intermediates play a crucial role in the cross coupling of epoxides and alkynes.
The approach highlights the importance of transition-metal catalysis in modern organic synthesis.

Implication

This method demonstrates effective cross coupling using radical anions in organic synthesis, indicating a new route for epoxides and alkynes.

Abstract

Epoxides are versatile intermediates in organic synthesis due to the high ring strain of their three-membered oxirane structure. While the classical two-electron ring-opening of epoxides with nucleophiles or through transition-metal...

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Cite This Study

Yang et al. (2025) studied this question.

synapsesocial.com/papers/68e9b2e4ba7d64b6fc13309c https://doi.org/10.1039/d5gc03812j

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Implication

This method demonstrates effective cross coupling using radical anions in organic synthesis, indicating a new route for epoxides and alkynes.

Photoinduced copper-catalyzed cross coupling of epoxides and alkynes via radical anions

Key Points

Implication

Abstract

Discussion

Cite This Study

Photoinduced copper-catalyzed cross coupling of epoxides and alkynes via radical anions

Key Points

Implication

Abstract

Discussion

Cite This Study

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