Isolation of Ce(IV) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency

Dominic Shiels; Mario Pittalis; Nadeeshan Gunarathna; Adriana C Berlfein; William W. Brennessel; Michael T. Ruggiero; Ellen M. Matson

doi:10.1039/d5sc06415e

January 1, 2025Chemical ScienceOpen Access

Isolation of Ce(IV) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency

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Key Points

The study reveals distinctive redox properties of a Ce(III) centered sandwich-type complex.
Cyclic voltammetry data suggests significant differences in metal-oxygen covalency.
The investigation focuses on comparing the covalent nature of new Ce(IV) complexes.
Insights into the metal-oxygen bond may influence future materials development.

Implication

Investigation reveals redox properties of Ce(III) centered polyoxoalkoxide complexes, indicating covalent characteristics.

Abstract

The new CeIII centered sandwich-type complex (TBA)3[Ce{W4O13(OMe)4MoNO}2] is reported. The redox properties of this molecule, and its all-molybdenum analogue, (TBA)3[Ce{Mo5O13(OMe)4NO}2], were investigated using cyclic voltammetry. The data reveals the presence...

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Cite This Study

Shiels et al. (2025) studied this question.

synapsesocial.com/papers/68efa18f9d05deea71d13f84 https://doi.org/10.1039/d5sc06415e

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Isolation of Ce(IV) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency

Key Points

Implication

Abstract

Discussion

Cite This Study

Isolation of Ce(IV) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency

Key Points

Implication

Abstract

Discussion

Cite This Study

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