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This is a Experimental Study study.

October 15, 2025Chemical Communications

Photoinduced EDA complex triggered difluoroalkylation of quinoxalin-2(1H)-ones with unactivated alkenes and fluoroalkyl bromides

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This method successfully achieved difluoroalkylation, expanding synthetic options for complex molecules.
Key outcomes include formation of new bonds using readily available reactants, showing versatility.
The strategy utilizes an EDA mechanism to initiate the reaction under mild conditions.
Findings suggest this reaction could streamline synthesis in organic chemistry.

Implication

This reaction demonstrates difluoroalkylation using unactivated alkenes and fluoroalkyl bromides, indicating a metal-free approach.

Abstract

A metal-free photo-induced three-component difluoroalkylation reaction between quinoxalin-2(1H)‑ones, unactivated alkenes with fluoroalkyl bromides via EDA strategy has been reported. This reaction was initiated by the photochemistry of electron donor acceptor...

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Cite This Study

Cui et al. (2025) studied this question.

synapsesocial.com/papers/68eff7392ae617e5891a918f https://doi.org/10.1039/d5cc04758g

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Implication

This reaction demonstrates difluoroalkylation using unactivated alkenes and fluoroalkyl bromides, indicating a metal-free approach.

Photoinduced EDA complex triggered difluoroalkylation of quinoxalin-2(1H)-ones with unactivated alkenes and fluoroalkyl bromides

Key Points

Implication

Abstract

Discussion

Cite This Study

Photoinduced EDA complex triggered difluoroalkylation of quinoxalin-2(1H)-ones with unactivated alkenes and fluoroalkyl bromides

Key Points

Implication

Abstract

Discussion

Cite This Study

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