Fluorocarbon Interfacial Modifier: Wettability Alteration in Reservoir Rocks for Enhanced Oil Recovery and Field Application

The peripheral reservoirs of the Daqing Oilfield exhibit low permeability and partial heterogeneity, resulting in a rapid injection pressure increase, limited sweep efficiency, and significant residual oil retention. To enhance recovery, this study synthesized a fluorocarbon siloxane (FHB) via free radical addition for rock surface wettability modification. At a concentration of 0.1 wt%, FHB increased water and oil contact angles to 136° and 117°, respectively, at 60 °C. Fourier transform infrared spectroscopy, thermogravimetric analysis, and aging tests confirmed stable hydrophobic/oleophobic properties through chemical bonding to the rock. Furthermore, the low surface energy FHB significantly reduced adhesion work and decreased oil-water interfacial tension from 27 mN/m to 0.55 mN/m, thereby improving fluid transport in pore throats and promoting residual oil mobilization. Core flooding experiments resulted in an increase in total recovery by 11%, with low-field NMR analysis confirming reduced oil saturation across various pore sizes. A field trial in a production well in Daqing Oilfield successfully increased output from 3.1 t/d to 4.9 t/d, validating the efficacy of this strategy under real reservoir conditions—representing the first successful field application of a fluorocarbon-based modifier for wettability alteration and oil production enhancement in China. This study provides valuable experimental data and a practical framework for implementing chemical-enhanced recovery.