An icosahedral Au ₁₃ nanocluster with three adjacent chlorides on opposite poles catalyses hydroamination of phenylacetylene

Shen Wu; Tatsuya TSUKUDA; Shinjiro Takano

doi:10.1039/d5cp03444b

January 1, 2025Physical Chemistry Chemical Physics

An icosahedral Au ₁₃ nanocluster with three adjacent chlorides on opposite poles catalyses hydroamination of phenylacetylene

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Key Points

Catalysis performance of the nanocluster indicates increased efficiency in hydroamination reactions.
The novel synthesis involved a diphosphine ligand to form the anionic gold nanocluster structure.
Characterization via single-crystal X-ray diffraction demonstrated precise molecular arrangement.
The findings suggest a promising application in catalytic processes for phenylacetylene synthesis.

Implication

The synthesized nanocluster enhances hydroamination of phenylacetylene, indicating significant catalytic potential.

Abstract

A novel anionic gold nanocluster [Au 13 (dppeF) 3 Cl 6 ] – bearing six chlorides has been synthesized by using a bulky diphosphine, dppeF (1,2-bis[bis(3,5-ditrifluoromethylphenyl)phosphino]ethane), as protecting ligands. Single-crystal X-ray diffraction analysis of this nanocluster revealed...

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Cite This Study

Wu et al. (2025) studied this question.

synapsesocial.com/papers/6925572cc0ce034ddc35a7ea https://doi.org/10.1039/d5cp03444b

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An icosahedral Au ₁₃ nanocluster with three adjacent chlorides on opposite poles catalyses hydroamination of phenylacetylene

Key Points

Implication

Abstract

Discussion

Cite This Study

An icosahedral Au ₁₃ nanocluster with three adjacent chlorides on opposite poles catalyses hydroamination of phenylacetylene

Key Points

Implication

Abstract

Discussion

Cite This Study

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