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January 1, 2025Nanoscale

Sc(OTf) ₃ -Induced, Selective Removal of Alkynyl Ligands from Heteroleptic Au ₁₃ and Au ₃₈ Nanoclusters

Zengguang Huang Shinjiro Takano Tatsuya Tsukuda

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Abstract

The heteroleptic gold nanoclusters [Au 13 (dppe) 5 (PA) 2 ] 3+ (dppe = 1,2-bis(diphenylphosphino)ethane; PA – = phenylacetylide) and [Au 38 (PPh 3 ) 4 (PA) 20 ] 2+ underwent the removal of PA − and a [Au(PA) 2 ] − staple unit, respectively, via reaction with the Lewis acid,...

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Cite This Study

Huang et al. (2025) studied this question.

synapsesocial.com/papers/693231308e51979591dce982 https://doi.org/10.1039/d5nr03977k

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