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Nickel-catalyzed reaction generates open-chain guanidines through isocyanide insertion, implying new synthetic pathways.
Herein, a nickel-catalyzed isocyanide insertion reaction with aromatic amines under open-air conditions is disclosed. A number of open-chain guanidines are successfully synthesized in moderate to good yields and the structure...
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Zheng et al. (2025) studied this question.
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