2D Organic–Inorganic Halide Perovskites for Hybrid Heterostructures: Single Crystals, Thin Films and Exfoliated Flakes

Rapid progress on the fabrication of lead halide perovskite has led to the development of high performance optoelectronic devices, particularly in the field of solar cell technologies. This initial success has subsequently inspired investigations into layered 2D-halide perovskite structures, motivated in part by their good environmental stability, but more significantly by their intriguing fundamental photo-physics. They have recently been used to improve the photoresponsivity of monolayer transition metal dichalcogenides in hybrid heterostructures. In this paper, we report on the synthesis of the (PEA)2(MA)n−1PbnI3n+1 series (with n = 1, 2, 3) of 2D-halide perovskites, in order to develop a platform that provides ultra-thin layers for the fabrication of hybrid heterostructures. The crystal synthesis method and its basic structural and optical characterization are shown, highlighting the differences in the crystal synthesis processes. Furthermore, we explore the preparation of 2D halide perovskite ultra-thin flakes using the mechanical exfoliation method, and few-layer-areas of n = 1 member of the series are identified using atomic force microscopy. Finally, we study the deposition of thin and ultra-thin films using the spin coating technique to provide an alternative exfoliation process.