The method demonstrates regioselective transformation of allenols with phosphoric acid, suggesting new pathways for organosulfur compounds.
A chiral sulfide/B(C6F5)3/phosphoric acid co-catalyzed highly regio- and enantioselective tandem electrophilic sulfenylation/semipinacol rearrangement of allenols is developed for the first time. A variety of chiral organosulfur compounds bearing all-carbon quaternary...
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Wei et al. (2025) studied this question.
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