Optical investigation reveals spin-crossover properties in hydrated and dehydrated Fe(II) crystals, suggesting hydration impacts SCO behavior.
This study presents a comprehensive optical spectroscopic investigation of spin-crossover (SCO) behavior in the Fe(II) complex, [Fe(bppsipr)2](BF4)2 (where bppsipr = 4-(iso-propylsulfanyl)-2,6-bis(pyrazol-1-yl)pyridine), in both hydrated and dehydrated single-crystal forms. High-resolution single-crystal...
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Malcolm A. Halcrow (2025) studied this question.
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