What question did this study set out to answer?

This research aims to explore how hydration affects spin-state dynamics in iron(II) spin-crossover materials.

April 10, 2026

Hydration-driven Structural Reorganization and Switchable Thermal-Photoinduced Spin-State Dynamics in Iron(II) Spin-crossover Crystalline Solids

Key Points

This research aims to explore how hydration affects spin-state dynamics in iron(II) spin-crossover materials.
Conducted structural and spectroscopic investigations using single-crystal XRD
Analyzed the role of hydration in spin-state switching
Utilized comprehensive approaches to examine thermal and photoinduced effects
Demonstrated that hydration significantly influences spin-state switching dynamics
Outlined the structural changes accompanying the spin-state transitions
Provided insights into potential applications in smart materials

Abstract

We present a comprehensive structural and spectroscopic investigation of the Fe(II) spin-crossover (SCO) crystalline solid, Fe(3-bpp)22Cr(ox)3(ClO4)·5H2O, highlighting the pivotal role of hydration in governing spin-state switching dynamics. Single-crystal XRD at...

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Authors

Mousumi Dutta

Indian Institute of Technology Kharagpur

Ajana Dutta

Indian Institute of Technology Kharagpur

Pradip Chakraborty

Indian Institute of Technology Kharagpur

Journals

Dalton Transactions

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Hydration-driven Structural Reorganization and Switchable Thermal-Photoinduced Spin-State Dynamics in Iron(II) Spin-crossover Crystalline Solids

Key Points

Abstract

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Authors

Journals

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References and Citations

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