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Enantioselective cyclization improves alkoxycyclizations in bromo-1,6-enynes, suggesting better yields with chiral catalysts.
The first enantioselective gold(I)-catalyzed alkoxycyclization of bromo-1,6-enynes is achieved using a modified JohnPhos ligand with a distal C2-chiral 2,5-diarylpyrrolidine. By using a chiral catalyst of the same family, the enantioselective...
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Cataffo et al. (2026) studied this question.
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