A New Class of Customisable Stable Boronic Ester Assembly

Daniel Coomber; Olivia Rusli; Hemant Sharma; Peter Lee; Jack D. Evans; Nicole Joy Rijs; Carol Hua; Frederick Matthew Pfeffer

doi:10.1039/d5sc08385k

January 1, 2026Chemical ScienceOpen Access

A New Class of Customisable Stable Boronic Ester Assembly

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Key Points

To create a new approach for assembling stable boronic ester macrocycles and cages using specific reactants.
Utilized fused polynorbornane based bis-diols and commercially available boronic acids.
Developed an efficient assembly process for covalent structures.
Explored the versatility of the assembly method in creating different architectures.
Successfully created a variety of stable macrocyclic and cage structures.
Demonstrated the customizability of the assembly process for different applications.
Showed that the new method is efficient compared to existing techniques.

Implication

Developing a customisable assembly technique enhances covalent macrocycle and cage creation, indicating versatility in chemical synthesis.

Abstract

An efficient, customisable approach for the assembly of covalent macrocycles and cages has been developed using the reaction of fused polynorbornane based bis-diols and commercially available boronic acids. The ability...

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Cite This Study

Coomber et al. (2026) studied this question.

synapsesocial.com/papers/698d6ebb5be6419ac0d547dc https://doi.org/10.1039/d5sc08385k

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A New Class of Customisable Stable Boronic Ester Assembly

Key Points

Implication

Abstract

Discussion

Cite This Study

A New Class of Customisable Stable Boronic Ester Assembly

Key Points

Implication

Abstract

Discussion

Cite This Study

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