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February 26, 2026Organic Chemistry Frontiers0 citations

Enantioselective synthesis of atropisomeric biaryls and heterobiaryls via transition metal-catalyzed cyclization

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SLShibo LinYZYa ZouSichuan UniversityYCYiwen Chu

Key Points

  • The aim is to develop an enantioselective synthesis method for atropisomeric biaryls and heterobiaryls using transition metal catalysis.
  • Utilized transition metal-catalyzed cyclization techniques.
  • Focused on creating asymmetric structures with a chiral axis.
  • Targeted the synthesis of biologically relevant molecules.
  • Successfully synthesized various atropisomeric biaryls and heterobiaryls.
  • Demonstrated high enantioselectivity in the synthesis process.
  • Showed potential applications for newly synthesized compounds in catalysis.

Abstract

Atropisomeric architectures with a chiral axis are prevalent in biologically active molecules and natural products, and they are widely put to use in privileged catalysts and chiral ligands. Axially chiral...

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Cite This Study

Lin et al. (2026) studied this question.

synapsesocial.com/papers/699fe3f995ddcd3a253e82c1https://doi.org/10.1039/d5qo01492a
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