Answers are grounded in this paper and cite their sources.
Research examines thermal decomposition outcomes of double complex salts in various atmospheres, suggesting new production methods for nanoalloys.
New double complex salts [Ir(NH)][Fe(CN)]·12HO and [Rh(NH)][Fe(CN)]·12HO were synthesized and structurally characterized for the first time. The thermal behavior of the synthesized salts in reducing (He/H), inert (He) and oxidizing (Ar/O) atmospheres was studied in detail. The final product of decomposition of the double complex salts [Ir(NH)][Fe(CN)]·12HO in reducing and inert atmospheres is a mixture of face-centered cubic and hexagonal close-packed nanosized solid solutions of Ir-Fe, and amorphous carbon. The decomposition of [Rh(NH)][Fe(CN)]·12HO in the same atmospheres leads to the formation of a mixture of ordered and disordered Rh-Fe nanoalloys containing amorphous carbon. In an oxidizing atmosphere, a mixture of metal oxides and metallic iridium (or rhodium) is formed. Based on the data obtained, thermal decomposition of [Ir(NH)][Fe(CN)]·12HO and [Rh(NH)][Fe(CN)]·12HO can be considered as a method for producing nanoalloys or oxide systems based on iron and iridium (rhodium).
No takes yet. Share an insight, caveat, or question.
A.A. Popov (2025) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: