Electrochemical Approaches Toward Arylation Reactions

Electrochemical arylation has emerged as a sustainable and efficient approach for forming CC and Cheteroatom bonds. These reactions provide a green alternative to conventional arylation methods that often rely on harsh reaction conditions. The present review categorizes electrochemical arylation reactions into key types, such as C–H arylation, α ‐arylation, oxidative arylation, reductive arylation, decarboxylative arylation, O ‐arylation, and other miscellaneous transformations. Each class highlights distinct mechanistic features and substrate scopes, demonstrating the versatility of electrochemical techniques in constructing diverse arylated frameworks. Overall, this review provides a comprehensive understanding of how electrochemical strategies are revolutionizing arylation chemistry and paving the way toward more sustainable organic synthesis.