What question did this study set out to answer?

To develop an efficient and general method for synthesizing γ-sultines from unactivated alkenes.

March 10, 2026Angewandte Chemie

Modular and Direct Synthesis of γ‐Sultines From Simple Unactivated Alkenes

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To develop an efficient and general method for synthesizing γ-sultines from unactivated alkenes.
Utilized visible light-driven relay to convert alkenes into γ-sultines.
Employed sulfoxonium ylides and DABSO as SO2 source.
Generated electrophilic distonic radical cation for reaction initiation.
Incorporated radical relay and cyclization in a single photochemical sequence.
Successfully synthesized γ-sultines from simple unactivated alkenes.
Demonstrated broad substrate scope and excellent functional-group tolerance.
New method is applicable for late-stage functionalization of complex molecules.

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Implication

This research demonstrates a novel method to synthesize γ-sultines from simple alkenes, suggesting new pathways for complex molecule functionalization.

Cite This Study

Huang et al. (2026) studied this question.

synapsesocial.com/papers/69af95a470916d39fea4d6a5 https://doi.org/10.1002/ange.202522431

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Implication

This research demonstrates a novel method to synthesize γ-sultines from simple alkenes, suggesting new pathways for complex molecule functionalization.

Modular and Direct Synthesis of γ‐Sultines From Simple Unactivated Alkenes

Key Points

Discussion

Implication

Cite This Study

Modular and Direct Synthesis of γ‐Sultines From Simple Unactivated Alkenes

Key Points

Discussion

Implication

Cite This Study

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