This work demonstrates synthesis and reactivity of cerium(IV) amidinate complexes, indicating potential for salt metathesis applications.
We present an isostructural series of cerium(IV) amidinate complexes with halide co-ligands ranging from fluoride to iodide. Different routes are presented to access these valuable species, including the use of various oxidants such as the trichloride salt [NEt3Me][Cl3] or the tribromide salt [NMe3Ph][Br3]. In addition, we present the syntheses of rare triflate and cationic cerium(IV) complexes and first insights into the salt metathesis reactivity using (thio-)cyanates and azides are given.
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Baltrun et al. (2026) studied this question.
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