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Demonstrates a nickel-catalyzed reaction that creates monofluoroarenes using gem-difluoroalkenes, indicating a new approach in synthetic chemistry.
A nickel-catalyzed defluorinative [4+2] cycloaddition has been developed for the direct synthesis of monofluoroarenes. This method employs gem-difluoroalkenes as effective surrogates for scarce 1-fluoroalkyne precursors, thereby circumventing conventional late-stage aromatic...
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Wan et al. (2026) studied this question.
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