This process demonstrates enhanced regioselectivity in C-H activation and annulation, suggesting new synthetic pathways.
A Ru(II)-catalyzed peri-selective C-H activation/annulation of α-naphthylamines with alkylidene β-lactones and β-lactams provides rapid access to diverse tricyclic naphtho-fused medium-sized lactams. Here, regioselectivity is dictated by a free amine directing...
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Mondal et al. (2026) studied this question.
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