Developing a method for C(sp3)-C(sp3) bond formation using fluorinated alkyl zincs and dual catalysis, highlighting its potential applications.
The cross‐coupling of esters of N‐hydroxyphthalimide with fluorinated alkyl zinc reagents resulting in the C(sp 3 )−C(sp 3 ) bond formation is described. The method involves readily accessible perfluorinated and tetrafluorinated alkyl zinc bromides. The reaction is performed under copper and photoredox dual catalysis conditions.
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Imaev et al. (2026) studied this question.
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