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Abstract Self‐assembly of a trigonal building subunit with diaminotriazines (DAT) functional groups leads to a unique rod‐packing 3D microporous hydrogen‐bonded organic framework (HOF‐3). This material shows permanent porosity and demonstrates highly selective separation of C 2 H 2 /CO 2 at ambient temperature and pressure.
Li et al. (Thu,) studied this question.
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