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Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After CS bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa=hexafluoroacetylacetonate). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z503691_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Schneider et al. (2006) studied this question.
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