⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 1995Journal of the Chemical Society Chemical Communications

Synthesis and structure of Ba2InO3F: oxide/fluoride ordering in a new K2NiF4 superstructure

Richard L. Needs Mark T. Weller

View at Publisher

Ask AI

Bookmark

Share

Key Points

Synthesize the quaternary oxyfluoride Ba2InO3F and determine its crystal structure and anion arrangement.
Prepared polycrystalline samples of Ba2InO3F using solid-state chemical synthesis.
Characterized the crystal symmetry and atomic positions using crystallographic structural analysis.
Confirmed the formation of a distinct K2NiF4-type superstructure phase in Ba2InO3F.
Demonstrated long-range crystallographic ordering between oxide and fluoride anions across the lattice sites.

No abstract yet

We only have this paper's title and publication details.

Read it at the source→

Implication

Structural analysis reveals oxide-fluoride ordering in synthesized Ba2InO3F, indicating a novel K2NiF4 superstructure.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Needs et al. (1995) studied this question.

synapsesocial.com/papers/69d7d8f133ca018b39ae2f30 https://doi.org/10.1039/c39950000353

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1The Key Role of Monovalent Indium and Anionic Vacancies in Oxyfluorides Inducing Fluoride Ion Mobility and LuminescenceOriginal Research · 2026
2Structure and magnetic properties of [Ni - O] exchange-coupled pairs in a single crystal of BaFOriginal Research · 2025
3High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Acentric Borate Fluoride: Ba<sub>2</sub>B<sub>5</sub>O<sub>9</sub>F·0.5H<sub>2</sub>OOriginal Research · 2018 · 5 citations
4Anion Exchange in LaBaInO3F2: Structural and Optical Effects of Low-Temperature Topochemical Modification2025
5A new cation- and vacancy-ordered Brownmillerite in the Ba–In–Fe–O system revealing hidden order in its cubic counterpartOriginal Research · 2026

More related papers

Revealing the Structure of Barium Oxyfluoroborate Glasses Using Molecular Dynamics, Total Neutron Scattering, and Nuclear Magnetic Resonance2026
Rare‐Earth‐Induced Fluoride‐Rich Local Structures Governing BaF <sub>2</sub> Nanocrystallization in Oxyfluoride Glasses2026
Synthesis of the Double Infinite-Layer Ni(I) Phase La <sub>3</sub> Ni <sub>2</sub> O <sub>5</sub> F via Sequential Topochemical Reactions2026

More from Journal of the Chemical Society Chemical Communications

A new MAS NMR probe for in situ investigations of hydrocarbon conversion on solid catalysts under continuous-flow conditionsSun,
Formation of methanol by the gas phase partial oxidation of methane under normal pressuresSun,