Tetrylidyne Coordination Modes: Vinyl-Type Germa-Ruthena Anion [Ru=Ge:] -and its Reaction with Monofluorobenzene

Frederic Seeger; Liesa Renz; Lars Wesemann

doi:10.1039/d6cc01226d

January 1, 2026Chemical CommunicationsOpen Access

Tetrylidyne Coordination Modes: Vinyl-Type Germa-Ruthena Anion [Ru=Ge:] -and its Reaction with Monofluorobenzene

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Key Points

The research aims to explore the new coordination modes of a ruthenium germyl complex and its interactions with monofluorobenzene.
Synthesis of ruthenium germyl complex (1) with monofluorobenzene
Reduction of (1) with four electrons
Examination of the resulting vinyl anion type complex (3a)
Vinyl anion complex (3a) demonstrates a novel coordination mode
Unique interaction with monofluorobenzene leads to new chemical insights

Implication

Experiments reveal a novel coordination mode in ruthenium germyl complexes, suggesting new chemistry with monofluorobenzene.

Abstract

Ruthenium germyl complex [(Ph3P)ClRuGeCl2(C6H3-2-{η 6 -Trip}-6-Trip)] (1) is reduced with four electrons to yield the vinyl anion type complex [(Ph3P)Ru=GeK(C6H3-2-{η 6 -Trip}-6-Trip)] (3a) exhibiting a novel coordination mode for a...

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Cite This Study

Seeger et al. (2026) studied this question.

synapsesocial.com/papers/69d894526c1944d70ce053db https://doi.org/10.1039/d6cc01226d

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Tetrylidyne Coordination Modes: Vinyl-Type Germa-Ruthena Anion [Ru=Ge:] -and its Reaction with Monofluorobenzene

Key Points

Implication

Abstract

Discussion

Cite This Study

Tetrylidyne Coordination Modes: Vinyl-Type Germa-Ruthena Anion [Ru=Ge:] -and its Reaction with Monofluorobenzene

Key Points

Implication

Abstract

Discussion

Cite This Study

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