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A well-formulated electrolyte is proposed based on a fluorinated carboxylate ester solvent, which shows a wide electrochemical window (0-4.73 V, vs. Li⁺/Li), low solvation energy (10.05 kJ mol⁻¹) and ability to maintain a liquid state at temperatures as low as -120 °C. This electrolyte produced batteries with superior electrochemical performance at low temperatures relative to carbonate-based electrolytes.
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Yang et al. (2020) studied this question.
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